Tetranuclear organometallic complexes based on 1,2-ethanedithiolate ligands as potential precursors for CuMS2 (M = Ga, In).
Identifieur interne : 000333 ( Main/Exploration ); précédent : 000332; suivant : 000334Tetranuclear organometallic complexes based on 1,2-ethanedithiolate ligands as potential precursors for CuMS2 (M = Ga, In).
Auteurs : RBID : pubmed:23677319English descriptors
- KwdEn :
- Copper (chemistry), Ethane (analogs & derivatives), Ethane (chemistry), Gallium (chemistry), Indium (chemistry), Ligands, Models, Molecular, Molecular Structure, Organometallic Compounds (chemical synthesis), Organometallic Compounds (chemistry), Sulfhydryl Compounds (chemistry), Sulfur (chemistry).
- MESH :
- chemical , analogs & derivatives : Ethane.
- chemical , chemical synthesis : Organometallic Compounds.
- chemical , chemistry : Copper, Ethane, Gallium, Indium, Organometallic Compounds, Sulfhydryl Compounds, Sulfur.
- chemical : Ligands.
- Models, Molecular, Molecular Structure.
Abstract
The synthesis and characterization of a series of homologous tetranuclear complexes [((i)Pr3PCu)2(MR2)2(SCH2CH2S)2] (MR2 = GaMe2 (2), GaEt2 (3), Ga(i)Pr2 (4), Ga(n)Bu2 (5) and InMe2 (6), InEt2 (7), In(i)Pr2 (8), In(n)Bu2 (9)) and of related compounds [((i)Pr3PCu)3(MR2)(SCH2CH2S)2] (MR2 = GaMe2 (10), GaEt2 (11), Ga(i)Pr2 (12), Ga(n)Bu2 (13) and InMe2 (14), InEt2 (15), In(i)Pr2 (16), In(n)Bu2 (17)) are presented. The molecular structures of these were determined by single crystal X-ray diffraction. Thermolysis processes of all the representatives of 2-9 were investigated by simultaneous thermal analysis and thermal decomposition in a nitrogen atmosphere in a quartz glass tube. According to powder X-ray diffraction studies these thermolysis residues predominantly consist of CuMS2 (M = Ga, In), which mainly occurred in the well known tetragonal chalcopyrite-type structure and partially in the hexagonal wurtzite-type structure. As expected from their composition, representatives of 10-17 form mixtures of CuMS2 and large amounts of Cu(2-x)S upon thermolysis.
DOI: 10.1039/c3dt50461a
PubMed: 23677319
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Tetranuclear organometallic complexes based on 1,2-ethanedithiolate ligands as potential precursors for CuMS2 (M = Ga, In).</title><author><name sortKey="Friedrich, Dirk" uniqKey="Friedrich D">Dirk Friedrich</name><affiliation wicri:level="3"><nlm:affiliation>Universität Leipzig, Institut für Anorganische Chemie, Johannisallee 29, 04103 Leipzig, Germany.</nlm:affiliation><country xml:lang="fr">Allemagne</country><wicri:regionArea>Universität Leipzig, Institut für Anorganische Chemie, Johannisallee 29, 04103 Leipzig</wicri:regionArea><placeName><region type="land" nuts="1">Saxe (Land)</region><region type="district" nuts="2">District de Leipzig</region><settlement type="city">Leipzig</settlement></placeName></affiliation></author><author><name sortKey="Kluge, Oliver" uniqKey="Kluge O">Oliver Kluge</name></author><author><name sortKey="Kischel, Marcus" uniqKey="Kischel M">Marcus Kischel</name></author><author><name sortKey="Krautscheid, Harald" uniqKey="Krautscheid H">Harald Krautscheid</name></author></titleStmt><publicationStmt><date when="2013">2013</date><idno type="doi">10.1039/c3dt50461a</idno><idno type="RBID">pubmed:23677319</idno><idno type="pmid">23677319</idno><idno type="wicri:Area/Main/Corpus">000617</idno><idno type="wicri:Area/Main/Curation">000617</idno><idno type="wicri:Area/Main/Exploration">000333</idno></publicationStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Copper (chemistry)</term><term>Ethane (analogs & derivatives)</term><term>Ethane (chemistry)</term><term>Gallium (chemistry)</term><term>Indium (chemistry)</term><term>Ligands</term><term>Models, Molecular</term><term>Molecular Structure</term><term>Organometallic Compounds (chemical synthesis)</term><term>Organometallic Compounds (chemistry)</term><term>Sulfhydryl Compounds (chemistry)</term><term>Sulfur (chemistry)</term></keywords><keywords scheme="MESH" type="chemical" qualifier="analogs & derivatives" xml:lang="en"><term>Ethane</term></keywords><keywords scheme="MESH" type="chemical" qualifier="chemical synthesis" xml:lang="en"><term>Organometallic Compounds</term></keywords><keywords scheme="MESH" type="chemical" qualifier="chemistry" xml:lang="en"><term>Copper</term><term>Ethane</term><term>Gallium</term><term>Indium</term><term>Organometallic Compounds</term><term>Sulfhydryl Compounds</term><term>Sulfur</term></keywords><keywords scheme="MESH" type="chemical" xml:lang="en"><term>Ligands</term></keywords><keywords scheme="MESH" xml:lang="en"><term>Models, Molecular</term><term>Molecular Structure</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The synthesis and characterization of a series of homologous tetranuclear complexes [((i)Pr3PCu)2(MR2)2(SCH2CH2S)2] (MR2 = GaMe2 (2), GaEt2 (3), Ga(i)Pr2 (4), Ga(n)Bu2 (5) and InMe2 (6), InEt2 (7), In(i)Pr2 (8), In(n)Bu2 (9)) and of related compounds [((i)Pr3PCu)3(MR2)(SCH2CH2S)2] (MR2 = GaMe2 (10), GaEt2 (11), Ga(i)Pr2 (12), Ga(n)Bu2 (13) and InMe2 (14), InEt2 (15), In(i)Pr2 (16), In(n)Bu2 (17)) are presented. The molecular structures of these were determined by single crystal X-ray diffraction. Thermolysis processes of all the representatives of 2-9 were investigated by simultaneous thermal analysis and thermal decomposition in a nitrogen atmosphere in a quartz glass tube. According to powder X-ray diffraction studies these thermolysis residues predominantly consist of CuMS2 (M = Ga, In), which mainly occurred in the well known tetragonal chalcopyrite-type structure and partially in the hexagonal wurtzite-type structure. As expected from their composition, representatives of 10-17 form mixtures of CuMS2 and large amounts of Cu(2-x)S upon thermolysis.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="MEDLINE"><PMID Version="1">23677319</PMID><DateCreated><Year>2013</Year><Month>06</Month><Day>12</Day></DateCreated><DateCompleted><Year>2013</Year><Month>10</Month><Day>31</Day></DateCompleted><DateRevised><Year>2013</Year><Month>11</Month><Day>21</Day></DateRevised><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1477-9234</ISSN><JournalIssue CitedMedium="Internet"><Volume>42</Volume><Issue>26</Issue><PubDate><Year>2013</Year><Month>Jul</Month><Day>14</Day></PubDate></JournalIssue><Title>Dalton transactions (Cambridge, England : 2003)</Title><ISOAbbreviation>Dalton Trans</ISOAbbreviation></Journal><ArticleTitle>Tetranuclear organometallic complexes based on 1,2-ethanedithiolate ligands as potential precursors for CuMS2 (M = Ga, In).</ArticleTitle><Pagination><MedlinePgn>9613-20</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1039/c3dt50461a</ELocationID><Abstract><AbstractText>The synthesis and characterization of a series of homologous tetranuclear complexes [((i)Pr3PCu)2(MR2)2(SCH2CH2S)2] (MR2 = GaMe2 (2), GaEt2 (3), Ga(i)Pr2 (4), Ga(n)Bu2 (5) and InMe2 (6), InEt2 (7), In(i)Pr2 (8), In(n)Bu2 (9)) and of related compounds [((i)Pr3PCu)3(MR2)(SCH2CH2S)2] (MR2 = GaMe2 (10), GaEt2 (11), Ga(i)Pr2 (12), Ga(n)Bu2 (13) and InMe2 (14), InEt2 (15), In(i)Pr2 (16), In(n)Bu2 (17)) are presented. The molecular structures of these were determined by single crystal X-ray diffraction. Thermolysis processes of all the representatives of 2-9 were investigated by simultaneous thermal analysis and thermal decomposition in a nitrogen atmosphere in a quartz glass tube. According to powder X-ray diffraction studies these thermolysis residues predominantly consist of CuMS2 (M = Ga, In), which mainly occurred in the well known tetragonal chalcopyrite-type structure and partially in the hexagonal wurtzite-type structure. As expected from their composition, representatives of 10-17 form mixtures of CuMS2 and large amounts of Cu(2-x)S upon thermolysis.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Friedrich</LastName><ForeName>Dirk</ForeName><Initials>D</Initials><Affiliation>Universität Leipzig, Institut für Anorganische Chemie, Johannisallee 29, 04103 Leipzig, Germany.</Affiliation></Author><Author ValidYN="Y"><LastName>Kluge</LastName><ForeName>Oliver</ForeName><Initials>O</Initials></Author><Author ValidYN="Y"><LastName>Kischel</LastName><ForeName>Marcus</ForeName><Initials>M</Initials></Author><Author ValidYN="Y"><LastName>Krautscheid</LastName><ForeName>Harald</ForeName><Initials>H</Initials></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType>Journal Article</PublicationType><PublicationType>Research Support, Non-U.S. Gov't</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2013</Year><Month>05</Month><Day>15</Day></ArticleDate></Article><MedlineJournalInfo><Country>England</Country><MedlineTA>Dalton Trans</MedlineTA><NlmUniqueID>101176026</NlmUniqueID><ISSNLinking>1477-9226</ISSNLinking></MedlineJournalInfo><ChemicalList><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>1,2-ethanedithiolate</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Ligands</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Organometallic Compounds</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Sulfhydryl Compounds</NameOfSubstance></Chemical><Chemical><RegistryNumber>045A6V3VFX</RegistryNumber><NameOfSubstance>Indium</NameOfSubstance></Chemical><Chemical><RegistryNumber>70FD1KFU70</RegistryNumber><NameOfSubstance>Sulfur</NameOfSubstance></Chemical><Chemical><RegistryNumber>789U1901C5</RegistryNumber><NameOfSubstance>Copper</NameOfSubstance></Chemical><Chemical><RegistryNumber>CH46OC8YV4</RegistryNumber><NameOfSubstance>Gallium</NameOfSubstance></Chemical><Chemical><RegistryNumber>L99N5N533T</RegistryNumber><NameOfSubstance>Ethane</NameOfSubstance></Chemical></ChemicalList><CitationSubset>IM</CitationSubset><MeshHeadingList><MeshHeading><DescriptorName MajorTopicYN="N">Copper</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Ethane</DescriptorName><QualifierName MajorTopicYN="Y">analogs & derivatives</QualifierName><QualifierName MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Gallium</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Indium</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Ligands</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Models, Molecular</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Molecular Structure</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Organometallic Compounds</DescriptorName><QualifierName MajorTopicYN="N">chemical synthesis</QualifierName><QualifierName MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Sulfhydryl Compounds</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Sulfur</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName></MeshHeading></MeshHeadingList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="aheadofprint"><Year>2013</Year><Month>5</Month><Day>15</Day></PubMedPubDate><PubMedPubDate PubStatus="epublish"><Year>2013</Year><Month>6</Month><Day>12</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2013</Year><Month>5</Month><Day>17</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2013</Year><Month>5</Month><Day>17</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2013</Year><Month>11</Month><Day>1</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="doi">10.1039/c3dt50461a</ArticleId><ArticleId IdType="pubmed">23677319</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
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